NIOSH Pocket Guide to Chemical Hazards

2-Butoxyethanol CAS 111-76-2
C4H9OCH2CH2OH RTECS KJ8575000
Synonyms & Trade Names
Butyl Cellosolve®, Butyl oxitol, Dowanol® EB, EGBE, Ektasolve EB®, Ethylene glycol monobutyl ether, Jeffersol EB
DOT ID & Guide
2369 152
Exposure
Limits
NIOSH REL: TWA 5 ppm (24 mg/m3) [skin]
OSHA PEL�: TWA 50 ppm (240 mg/m3) [skin]
IDLH 700 ppm Conversion 1 ppm = 4.83 mg/m3
Physical Description
Colorless liquid with a mild, ether-like odor.
MW: 118.2
BP: 339°F
FRZ: -107°F
Sol: Miscible
VP: 0.8 mmHg
IP: 10.00 eV

Sp.Gr: 0.90
Fl.P: 143°F
UEL(275°F): 12.7%
LEL(200°F): 1.1%

Class IIIA Combustible Liquid: Fl.P. at or above 140�F and below 200�F.
Incompatibilities & Reactivities
Strong oxidizers, strong caustics
Measurement Methods
NIOSH 1403; OSHA 83
Personal Protection & Sanitation
Skin: Prevent skin contact
Eyes: Prevent eye contact
Wash skin: When contaminated
Remove: When wet or contaminated
Change: No recommendation
Provide: Quick drench
First Aid (See procedures)
Eye: Irrigate immediately
Skin: Soap wash promptly
Breathing: Respiratory support
Swallow: Medical attention immediately
Respirator Recommendations NIOSH
Up to 50 ppm: (APF = 10) Any chemical cartridge respirator with organic vapor cartridge(s)*/(APF = 10) Any supplied-air respirator*
Up to 125 ppm: (APF = 25) Any supplied-air respirator operated in a continuous-flow mode*/(APF = 25) Any powered, air-purifying respirator with organic vapor cartridge(s)*
Up to 250 ppm: (APF = 50) Any chemical cartridge respirator with a full facepiece and organic vapor cartridge(s)/(APF = 50) Any air-purifying, full-facepiece respirator (gas mask) with a chin-style, front- or back-mounted organic vapor canister/(APF = 50) Any powered, air-purifying respirator with a tight-fitting facepiece and organic vapor cartridge(s)*/(APF = 50) Any self-contained breathing apparatus with a full facepiece/(APF = 50) Any supplied-air respirator with a full facepiece
Up to 700 ppm: (APF = 2000) Any supplied-air respirator that has a full facepiece and is operated in a pressure-demand or other positive-pressure mode
Emergency or planned entry into unknown concentrations or IDLH conditions: (APF = 10,000) Any self-contained breathing apparatus that has a full facepiece and is operated in a pressure-demand or other positive-pressure mode/(APF = 10,000) Any supplied-air respirator that has a full facepiece and is operated in a pressure-demand or other positive-pressure mode in combination with an auxiliary self-contained positive-pressure breathing apparatus
Escape: (APF = 50) Any air-purifying, full-facepiece respirator (gas mask) with a chin-style, front- or back-mounted organic vapor canister/Any appropriate escape-type, self-contained breathing apparatus
Exposure Routes inhalation, skin absorption, ingestion, skin and/or eye contact
Symptoms Irritation eyes, skin, nose, throat; hemolysis, hematuria (blood in the urine); central nervous system depression, headache; vomiting
Target Organs Eyes, skin, respiratory system, central nervous system, hematopoietic system, blood, kidneys, liver, lymphoid system
See also: INTRODUCTION