NIOSH Pocket Guide to Chemical Hazards

Paraquat (Paraquat dichloride) CAS 1910-42-5
CH3(C5H4N)2CH3 • 2Cl RTECS DW2275000
Synonyms & Trade Names
1,1'-Dimethyl-4,4'-bipyridinium dichloride; N,N'-Dimethyl-4,4'-bipyridinium dichloride; Paraquat chloride; Paraquat dichloride [Note: Paraquat is a cation (C12H14N2++; 1,1-Dimethyl-4,4-bipyridinium ion); the commercial product is the dichloride salt of paraquat.]
DOT ID & Guide
Exposure
Limits
NIOSH REL: TWA 0.1 mg/m3 (resp) [skin]
OSHA PEL�: TWA 0.5 mg/m3 (resp) [skin]
IDLH 1 mg/m3 Conversion
Physical Description
Yellow solid with a faint, ammonia-like odor. [herbicide] [Note: Paraquat may also be found commercially as a methyl sulfate salt C12H14N2 • 2CH3SO4.]
MW: 257.2
BP: Decomposes
MLT: 572°F (Decomposes)
Sol: Miscible
VP: <0.0000001 mmHg
IP: ?

Sp.Gr: 1.24
Fl.P: NA
UEL: NA
LEL: NA

Noncombustible Solid
Incompatibilities & Reactivities
Strong oxidizers, alkylaryl-sulfonate wetting agents [Note: Corrosive to metals. Decomposes in presence of ultraviolet light.]
Measurement Methods
NIOSH 5003
Personal Protection & Sanitation
Skin: Prevent skin contact
Eyes: Prevent eye contact
Wash skin: When contaminated
Remove: When wet or contaminated
Change: No recommendation
Provide: Quick drench
First Aid (See procedures)
Eye: Irrigate immediately
Skin: Water flush immediately
Breathing: Respiratory support
Swallow: Medical attention immediately
Respirator Recommendations NIOSH
Up to 1 mg/m3: (APF = 10) Any chemical cartridge respirator with organic vapor cartridge(s) in combination with a dust, mist, and fume filter*/(APF = 25) Any powered, air-purifying respirator with organic vapor cartridge(s) in combination with a dust, mist, and fume filter*/(APF = 10) Any supplied-air respirator*/(APF = 50) Any self-contained breathing apparatus with a full facepiece
Emergency or planned entry into unknown concentrations or IDLH conditions: (APF = 10,000) Any self-contained breathing apparatus that has a full facepiece and is operated in a pressure-demand or other positive-pressure mode/(APF = 10,000) Any supplied-air respirator that has a full facepiece and is operated in a pressure-demand or other positive-pressure mode in combination with an auxiliary self-contained positive-pressure breathing apparatus
Escape: (APF = 50) Any air-purifying, full-facepiece respirator (gas mask) with a chin-style, front- or back-mounted organic vapor canister having a high-efficiency particulate filter/Any appropriate escape-type, self-contained breathing apparatus
Exposure Routes inhalation, skin absorption, ingestion, skin and/or eye contact
Symptoms Irritation eyes, skin, nose, throat, respiratory system; epistaxis (nosebleed); dermatitis; fingernail damage; irritation gastrointestinal tract; heart, liver, kidney damage
Target Organs Eyes, skin, respiratory system, heart, liver, kidneys, gastrointestinal tract
See also: INTRODUCTION